Diels-Alder approaches to pentacyclic triterpenes of the arborane and the fernane families

Autor:	Ricardo Rodriguez, Siméon Arseniyadis, Eric Guittet, Jose Camara, Loïc Toupet
Rok vydání:	1993
Předmět:	Diketone chemistry.chemical_classification Ketone Bicyclic molecule Diene Stereochemistry Organic Chemistry Alkylation Biochemistry chemistry.chemical_compound chemistry Drug Discovery Molecule Organic chemistry Pentacyclic Triterpenes Enone
Zdroj:	Tetrahedron Letters. 34:1141-1144
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)77511-3
Popis:	The high pressure Diels-Alder reaction of diene 2 and ene-dione 3 does not lead to the arborane skeleton but to angular isomers 5. The AB + D synthesis of tetracyclic ene-dione 6, followed by construction of the E-ring by a double alkylation, yields the isoarborinol precursor 7; the fernane series is similarly accessed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e0057bd31fe2d52bfeffb762259f0c70 https://doi.org/10.1016/s0040-4039(00)77511-3 Zobrazit plný text záznamu