Potential-Induced Degradation of CuIn$_{1-x} \hbox{Ga}_{x}$Se$_{2}$ Thin Film Solar Cells

Autor: Adam Hultqvist, T. Jarmar, Marika Edoff, Bruce G. Aitken, K. Fuller, K. Zhang, Pedro M. P. Salomé, Viktor Fjällström, Carlo Kosik Williams
Rok vydání: 2013
Předmět:
Zdroj: IEEE Journal of Photovoltaics. 3:1090-1094
ISSN: 2156-3403
2156-3381
DOI: 10.1109/jphotov.2013.2253833
Popis: The use of Na-free or low Na content glass substrates is observed to enhance the resiliency to potential-induced degradation, as compared with glass substrates with high Na content, such as soda lime glass (SLG). The results from stress tests in this study suggest that degradation caused by a combination of heat and bias across the SLG substrate is linked to increased Na concentration in the CdS and Cu(In,Ga)Se2 (CIGS) layers in CIGS-based solar cells. The degradation during the bias stress is dramatic. The efficiency drops to close to 0% after 50 h of stressing. On the other hand, cells on Na-free and low Na content substrates exhibited virtually no efficiency degradation. The degraded cells showed partial recovery by resting at room temperature without bias; thus, the degradation is nonpermanent and may be due to Na migration and accumulation rather than chemical reaction.
Databáze: OpenAIRE