Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Diynes with Isothiocyanates and Carbon Disulfide

Autor:	and Azusa Wada, Keiichi Noguchi, Ken Tanaka
Rok vydání:	2006
Předmět:	chemistry.chemical_compound Carbon disulfide Bicyclic molecule Chemistry Yield (chemistry) chemistry.chemical_element Organic chemistry General Medicine Cycloaddition Catalysis Rhodium BINAP
Zdroj:	ChemInform. 37
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200628130
Popis:	A neutral rhodium(I)/BINAP complex effectively catalyzed a [2+2+2] cycloaddition of 1,6-diynes with isothiocyanates to give bicyclic thiopyranimines in 59−98% isolated yield. The reaction with carb...
Databáze:	OpenAIRE
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