Metal complexes in the catalytic transformations of olefins. 5. Catalytic synthesis of C9-C24 olefins from propylene
Autor: | A. G. Pogorelov, T. V. Yanchevskaya, D. B. Furman, O. V. Bragin, A. Yu. Belyankin, Alexander Ivanov |
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Rok vydání: | 1992 |
Předmět: | |
Zdroj: | Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:1011-1014 |
ISSN: | 1573-9171 1063-5211 |
DOI: | 10.1007/bf00866575 |
Popis: | The optimum conditions for the production of C9-C24 olefins with yields of 20–25% (remainder hexenes) by oligomerization of liquid propylene at the Ni(PPh3)n (n=2–4)—Et3Al2Cl3 catalytic system were determined by simplex design of experiments. It was shown that the obtained hexenes undergo secondary di- and trimerization reactions. |
Databáze: | OpenAIRE |
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