Metal complexes in the catalytic transformations of olefins. 5. Catalytic synthesis of C9-C24 olefins from propylene

Autor: A. G. Pogorelov, T. V. Yanchevskaya, D. B. Furman, O. V. Bragin, A. Yu. Belyankin, Alexander Ivanov
Rok vydání: 1992
Předmět:
Zdroj: Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:1011-1014
ISSN: 1573-9171
1063-5211
DOI: 10.1007/bf00866575
Popis: The optimum conditions for the production of C9-C24 olefins with yields of 20–25% (remainder hexenes) by oligomerization of liquid propylene at the Ni(PPh3)n (n=2–4)—Et3Al2Cl3 catalytic system were determined by simplex design of experiments. It was shown that the obtained hexenes undergo secondary di- and trimerization reactions.
Databáze: OpenAIRE