Autor:	L. V. Grebenyuk, V. V. Kovalenko, K. Yu. Chotii, Grzegorz Schroeder, B. Lenska, V. I. Rybachenko, K. Eitner
Rok vydání:	2003
Předmět:	chemistry.chemical_compound chemistry Pyridine SN2 reaction Physical chemistry One stage Reactivity (chemistry) General Chemistry Acetonitrile Equilibrium constant
Zdroj:	Russian Journal of General Chemistry. 73:455-462
ISSN:	1070-3632
DOI:	10.1023/a:1024974323588
Popis:	Dimethylcarbamoyl transfer from N-acyloxypyridinium salts to pyridine N-oxides in acetonitrile occurs in one stage by the forced concerted SN2 mechanism. The rate and equilibrium of the reaction are fairly described by the Bronsted equation. The Marcus equation provides a much higher quality of reactivity predictions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dfa9dcbc7e53ca67068497876f58301f https://doi.org/10.1023/a:1024974323588 Zobrazit plný text záznamu Full text from SpringerLink