Effect of cesium nitrate and formiate additives on the properties of CO Conversion Cu-Zn-Al catalysts

Autor:	O. L. Ovsienko
Rok vydání:	2012
Předmět:	Inorganic chemistry Side reaction Oxide chemistry.chemical_element Copper Catalysis law.invention chemistry.chemical_compound chemistry Nitrate law Specific surface area Calcination Methanol
Zdroj:	Catalysis in Industry. 4:317-323
ISSN:	2070-0555 2070-0504
Popis:	The effect of cesium nitrate and formiate additives on the activity, crystalline structure, and specific surface area of the active copper component in coprecipitated Cu-Zn-Al catalyst for low-temperature CO conversion is studied. It is found that 1% Cs in the form of nitrate or formiate reduces catalyst activity in the side reaction of methanol synthesis by a factor of 2.5–3. The effect of cesium formiate on the crystalline structure and phase composition is less pronounced than that of nitrate. Introducing Cs into a carbonate mass is more advantageous than adding it to an oxide mass after calcination, since this leads to a greater decrease in the yield of methanol and a smaller change in the crystalline structure and phase composition of the catalyst.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dfa6794c50abc5b027b6d0c3957ecf71 https://doi.org/10.1134/s2070050412040137 Zobrazit plný text záznamu Full text from SpringerLink