A new radical mechanism of phorphyrin-photosensitized degradation reactions in biological systems
Autor: | M. P. Tsvirko, V. V. Gurinovich, A. V. Vorobei |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | High Energy Chemistry. 44:239-243 |
ISSN: | 1608-3148 0018-1439 |
DOI: | 10.1134/s001814391003015x |
Popis: | The feasibility of creation in biological membranes of artificial donor-acceptor systems, based on zinc porphyrins and halomethanes, capable of photoinduced electron transfer from excited porphyrin molecules to halomethane molecules has been shown. The radicals derived from halomethanes exhibit a high efficiency in the destructive action on the main membrane components proteins and lipids. |
Databáze: | OpenAIRE |
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