Rh(i)-Catalyzed intramolecular [2 + 2 + 1] cycloaddition of diynes with the N-terminal of the diazo group

Autor:	Jianbo Wang, Bo Wang, Yuankai Wang, Zixuan Wang
Rok vydání:	2019
Předmět:	010405 organic chemistry Organic Chemistry Migratory insertion 010402 general chemistry 01 natural sciences Medicinal chemistry Cycloaddition Reductive elimination 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Intramolecular force Moiety Diazo Carbene
Zdroj:	Organic Chemistry Frontiers. 6:2329-2333
ISSN:	2052-4129
Popis:	A new type of Rh(I)-catalyzed intramolecular [2 + 2 + 1] cycloaddition of diynes and the N-terminal of a diazo moiety is reported. This study is the first attempt to combine oxidative cyclometallation with carbene migratory insertion. This reaction is suggested to involve the initial oxidative cyclometallation, followed by migratory nitrogen insertion and reductive elimination.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::df7b195a97a2814a1585267f8897fbc8 https://doi.org/10.1039/c9qo00403c Zobrazit plný text záznamu