Photophysical properties of 3-(9-anthrylmethyl) pentane-2,4-dione

Autor:	Avinash V. Sapre, Avinash S. Kumbhar, Vitthal A. Kawade, Anupa A. Kumbhar
Rok vydání:	2013
Předmět:	chemistry.chemical_compound Anthracene Absorption spectroscopy chemistry Radiolysis General Physics and Astronomy Singlet state Physical and Theoretical Chemistry Ground state Excimer Photochemistry Fluorescence Diethylaniline
Zdroj:	Chemical Physics Letters. 583:198-202
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2013.07.071
Popis:	Photophysical properties of 3-(9-anthrylmethyl) pentane-2,4-dione (AMPD) have been studied using techniques of steady state optical absorption, fluorescence, time correlated single photon counting (TCSPC) and pulse radiolysis. Fluorescence spectrum of AMPD shows a structured emission in the region of 350–450 nm, typical of anthracene moiety. Singlet state energy of the AMPD molecule has been obtained as 306 kJ/mol. Addition of triethylamine (TEA) and diethylaniline (DEA) quenches the fluorescence of AMPD. Spectral features indicative of the ground state complex or exciplex formation were not observed for both the systems. Triplet–triplet absorption spectra were obtained using pulse radiolysis technique.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::df7773dbdeee9780dd24630e235bc88c https://doi.org/10.1016/j.cplett.2013.07.071 Zobrazit plný text záznamu Full Text from ScienceDirect