Bis[1,2-bis(diphenylphosphino)ethane]platinum(II) iodide bis(deuteriochloroform) solvate
| Autor: | Robert McCrindle, George Ferguson, Alan J. Lough, Alan J. McAlees |
|---|---|
| Rok vydání: | 1993 |
| Předmět: |
chemistry.chemical_classification
Hydrogen bond Stereochemistry Iodide Solvation chemistry.chemical_element General Medicine Crystal structure Ring (chemistry) Medicinal chemistry General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound 1 2-Bis(diphenylphosphino)ethane chemistry Molecule Platinum |
| Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 49:573-576 |
| ISSN: | 0108-2701 |
| DOI: | 10.1107/s0108270192010217 |
| Popis: | In the [(Ph 2 PCH 2 ) 2 ]Pt 2+ cation the Pt atom lies on a crys tallographic inversion centre (and has necessarily planar coordination) with Pt-P=2.3310(13) and 2.3250(14) A and intra-ring P-Pt-P=82.09(5) o . The unique five-membered PtP 2 C 2 ring has close to an enve lope conformation. The iodide ion lies in a general position and is hydrogen bonded to the deuterium of the teriochloroform of solvation with I...C=3.891(8), I...D=2.96 A and I...D-C=166 o |
| Databáze: | OpenAIRE |
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