Synthesis of 3-acyl-5-nitroisoxazoles on the base of geminal trinitro- and chlorodinitro-substituted pentan-2-one or 2-oximino-1-phenylbutan-1-one

Autor: V. G. Nikitin, A. A. Fainzil'berg, N. M. Lyapin, V. I. Slovetskii, G. Kh. Khisamutdinov
Rok vydání: 2009
Předmět:
Zdroj: Russian Chemical Bulletin. 58:2178-2181
ISSN: 1573-9171
1066-5285
DOI: 10.1007/s11172-009-0299-5
Popis: 3-Acyl-5-nitroisoxazoles were synthesized by heating 5,5,5-trinitropentan-2-one with LiCl in DMF at 100 °C as well as by heating oximino derivatives of 5,5,5-trinitro-, 5-chloro-5,5-dinitropentan-2-one or 4,4,4-trinitro- and 4-chloro-4,4-dinitro-1-phenylbutan-1-one in organic solvents.
Databáze: OpenAIRE