4-Vinylbenzyl chloride based porous spherical polymer supports derived from water-in-oil-in-water emulsions
| Autor: | Dejan Štefanec, Peter Krajnc |
|---|---|
| Rok vydání: | 2005 |
| Předmět: |
Polymers and Plastics
Chemistry Methylamine General Chemical Engineering technology industry and agriculture Stabiliser General Chemistry Biochemistry Chloride chemistry.chemical_compound Polymerization Chemical engineering Polymer chemistry Materials Chemistry medicine Environmental Chemistry Particle Hydroxymethyl Reactivity (chemistry) Particle size medicine.drug |
| Zdroj: | Reactive and Functional Polymers. 65:37-45 |
| ISSN: | 1381-5148 |
| DOI: | 10.1016/j.reactfunctpolym.2005.01.007 |
| Popis: | 4-Vinylbenzyl chloride (VBC) based water-in-oil-in-water emulsions with 85% pore volume and 70% VBC in organic phase were prepared and polymerised by free radical polymerisation. Porous spherical particles of diameters between 50 and 150 μm were obtained and their morphological structure and reactivity studied by FTIR spectroscopy, elemental analysis, optical microscopy, scanning electron microscopy and mercury intrusion porosimetry. Strong influence of the suspension stabiliser, namely poly(N-vinylpyrrolidone) (PVP), on the particle form was found. Diameters of spherical polymers particles depend on the PVP concentration, being larger with the lower concentration of PVP. Reactivity of novel supports was demonstrated by the reactions with piperidine, piperazine, tris(hydroxymethyl)methylamine and tris(2-aminoethyl)amine, all yielding corresponding amine derivatives. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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