Double-bowed nanoscale decanuclear copper(II) assemblies based on tartaric acid

Autor:	Wen-Wen Dong, Ya-Pan Wu, Yao-Yu Wang, Dong-Sheng Li, Jun Zhao, Qi-Zhen Shi
Rok vydání:	2010
Předmět:	Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Octahedron Hydrogen bond Materials Chemistry Tartaric acid Antiferromagnetism chemistry.chemical_element Physical and Theoretical Chemistry Nanoscopic scale Copper
Zdroj:	Inorganica Chimica Acta. 363:957-960
ISSN:	0020-1693
Popis:	The tartaric acid (H 4 L), serving as versatile tectons, link Cu II atoms with three different bridging modes to form a unique double-bowed nanosized Cu 10 -assembly, namely, [Cu II 10 (H 2 L) 4 (HL) 4 ]·(apy) 8 ·13H 2 O ( 1 ) (apy = 2-aminopyridine). Single-crystal analysis reveals that the nano-cluster is composed of two bow-shaped pentameric subunits joined together by carboxyl O bridges, in which eight Cu II atoms are in distorted octahedral site, while the other two Cu II atoms display the square-pyramidal geometries. Interestingly, such decanuclear SUBs are connected by R 2 2 (12) H-bonding rings into a 3D α -Po network. Magnetic studies show an antiferromagnetic interaction between Cu II centers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dee94c7f384d65d21b0bf5aa631ce415 https://doi.org/10.1016/j.ica.2009.12.032 Zobrazit plný text záznamu Full Text from ScienceDirect