Free radical and ionic reactions of (Benzoylmethyl)mercurials

Autor:	Glen A. Russell, S. V. Kulkarni, Rajive K. Khanna
Rok vydání:	2018
Předmět:	biology Radical Photodissociation Free-radical reaction Phenacyl Photochemistry Medicinal chemistry Adduct chemistry.chemical_compound Electron transfer chemistry biology.protein Organic anion Norbornene
Popis:	Photolysis of PhCOCH 2 HgCl or (PhCOCH 2 ) 2 Hg yields benzoylmethyl radicals which can be trapped by anions such as Me 2 C=NO 2 − , RC(CO 2 Et) 2 − , RC(O − )=CH 2 or by other electron-rich systems such as (RO) 3 P, N-methylpyrrole, enamines, or norbornene. Electron transfer from the adduct radicals to the mercurial yields PhCOCH 2 A from the anions A − , PhCOCH 2 P(O)(OR) 2 from P(OR) 3 , and the phenacyl derivative from N-methylpyrrole or enamines
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dee73d305d928fe4d794f45758447906 https://doi.org/10.31274/rtd-180813-12607 Zobrazit plný text záznamu