Phenoxo bridged dinuclear Zn(II) Schiff base complex as new precursor for preparation zinc oxide nanoparticles: Synthesis, characterization, crystal structures and photoluminescence studies
| Autor: | Marziyeh Mohammadi, Samira Saeednia, M. Hatefi Ardakani, Gh. Norouzi, Parvaneh Iranmanesh |
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| Rok vydání: | 2016 |
| Předmět: |
Thermogravimetric analysis
Materials science Nanostructure Schiff base 010405 organic chemistry Mechanical Engineering Inorganic chemistry chemistry.chemical_element Crystal structure Zinc 010402 general chemistry Condensed Matter Physics 01 natural sciences 0104 chemical sciences Crystallography chemistry.chemical_compound Differential scanning calorimetry chemistry Mechanics of Materials General Materials Science Thermal stability Powder diffraction |
| Zdroj: | Materials Research Bulletin. 78:1-10 |
| ISSN: | 0025-5408 |
| DOI: | 10.1016/j.materresbull.2016.02.010 |
| Popis: | Nanoparticles of a novel Zn(II) Schiff base complex, [Zn(HL)NO3]2 (1), (H2L = 2-[(2-hydroxy-propylimino) methyl] phenol), was synthesized by using solvothermal method. Shape, morphology and chemical structure of the synthesized nanoparticles were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Fourier Transform Infrared Spectoscopy (FT-IR) and UV–vis spectroscopy. Structural determination of compound 1 was determined by single-crystal X-ray diffraction. The results were revealed that the zinc complex is a centrosymmetric dimer in which deprotonated phenolates bridge the two five-coordinate metal atoms and link the two halves of the dimer. The thermal stability of compound 1 was analyzed by thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). The effect of the initial substrates concentration and reaction time on size and morphology of compound 1 nanostructure was investigated as well. Furthermore, the luminescent properties of the complex 1 were examined. ZnO nanoparticles with diameter between 15 and 20 nm were simply synthesized by solid-state transformation of compound 1 at 700 °C. |
| Databáze: | OpenAIRE |
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