Near infrared emission of Eu2+ ions in Ca3Sc2Si3O12

Autor:	V. P. Dotsenko, S. S. Smola, I. V. Berezovskaya, A. S. Voloshinovskii
Rok vydání:	2013
Předmět:	Materials science Doping Near-infrared spectroscopy Analytical chemistry General Physics and Astronomy Emission spectrum Physical and Theoretical Chemistry Atomic physics Luminescence Ion
Zdroj:	Chemical Physics Letters. 585:11-14
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2013.08.100
Popis:	The luminescent properties of Eu 2+ ions in Ca 3 Sc 2 Si 3 O 12 have been studied for the first time. The Eu 2+ -doped Ca 3 Sc 2 Si 3 O 12 exhibit a broadband emission in the 720–1100 nm region with a maximum at about 840 nm, which is due to the 4f 6 5d → 4f 7 transition of Eu 2+ ions. This interpretation is supported by the appearance of the fine structure in the emission spectrum of Eu 2+ -doped Ca 3 Sc 2 Si 3 O 12 at 77 K. Probably, the near infrared emission of Eu 2+ ions in Ca 3 Sc 2 Si 3 O 12 is the most long-wavelength 4f 6 5d → 4f 7 emission of these ions within more than three hundreds of Eu 2+ -doped inorganic compounds studied to date.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dec9a2043f2612ea14db1b9446a7a25d https://doi.org/10.1016/j.cplett.2013.08.100 Zobrazit plný text záznamu Full Text from ScienceDirect