Total asymmetric synthesis of polypropionate fragments and doubly branched heptono-1,4-lactones

Autor:	Pierre Vogel, Philippe Kernen
Rok vydání:	1993
Předmět:	chemistry.chemical_compound Nitrile chemistry Bicyclic molecule Stereochemistry Organic Chemistry Drug Discovery Rifamycin S Erythronolide-A Aldonic acid Enantioselective synthesis Enantiomer Biochemistry
Zdroj:	Tetrahedron Letters. 34:2473-2476
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)60444-6
Popis:	2-Cyano-1,5-dimethyl-7-oxabicyclo[2.2.1]hept-5-en-2-yl (1'R)-camphanate ((+)-3)and (+)-(1R,4R)-1,5-dimethyl-7-oxabicyclo[2.2.1]hept-5-en-2-one ((+)-4) were obtained readily from 3,4-dimethylfuran. (+)-3 was converted into 2,7-dideoxy-2,4-di-C-methyl-L-glycero- and D-glycero-L-altro-heptono-1,4-lactone ((+)-17) and ((+)-18).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::deb286ebb032ed43c764d4e5cf4a4bf2 https://doi.org/10.1016/s0040-4039(00)60444-6 Zobrazit plný text záznamu