Synthesis of AxC60 Film by Electrolysis

Autor: Hiroshi Yamamoto, Nobunari Yoshiyama, H. Endo
Rok vydání: 1996
Předmět:
Zdroj: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 280:289-294
ISSN: 1058-725X
DOI: 10.1080/10587259608040345
Popis: The electrolysis was adopted to obtain the AxC60 (A=Rb) film from an organic electrolyte solution including C60 molecules. The used solution was a mixture of 0.3mM-C60, 0.1N-RbClO4 and dimetyleformuamide (DMF) / Toluene (1:1). The particles in the obtained film had a spindle-like shape and grew up to the size of about 1μ m depending on the reaction temperature. The Raman spectra of the obtained films showed the existence of solid C60 and revealed the features of the polymeric RblC60, of which the crystal structure was confirmed a body-centered-orthorhombic phase by X-ray diffraction.
Databáze: OpenAIRE