Synthesis and structural studies of nickel(II) complexes of 14-membered trans-N2O2 and trans-N2S2 quadridentate macrocycles

Autor:	K. D. V. Weerasuria, Frederick S. Stephens, Paul A. Duckworth, Kevin P. Wainwright, S. Bruce Wild
Rok vydání:	1989
Předmět:	Stereochemistry chemistry.chemical_element Crystal structure Inorganic Chemistry Benzaldehyde chemistry.chemical_compound Nickel chemistry Polymer chemistry X-ray crystallography Molecule Physical and Theoretical Chemistry Triphenylphosphine Tetradentate ligand Diimine
Zdroj:	Inorganic Chemistry. 28:4531-4535
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00324a021
Popis:	Triphenylphosphine reacts with 2-(2-azidoethoxy)benzaldehyde in an aza-Wittig reaction to give the unsaturated 14-membered trans-N 2 O 2 diimine macrocycle 6,7,15,16-tetrahydrodibenzo[f,m][1,8,4,11]dioxadiazacyclotetradecine, presumably via seven-membered 2,3-dihydro-1,4-benzoxazepine
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::de9dd909aaecd8993bfb4863f4ce4155 https://doi.org/10.1021/ic00324a021 Zobrazit plný text záznamu