Bidimensional self-assembling of [HgII(RPhNNNPhR′)2] (R = acetyl, R′ = F) through metal-η4-arene π-interactions and non classical C–H⋯O bonding: Synthesis and X-ray characterization of a bis diaryl asymmetric-substituted triazenide complex polymer of Hg(II)
| Autor: | Johannes Beck, Lorenzo do Canto Visentin, Manfredo Hörner, Vinícius Feltrin Giglio, Gelson Manzoni de Oliveira, Fernanda Broch |
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| Rok vydání: | 2006 |
| Předmět: |
chemistry.chemical_classification
Stereochemistry X-ray Polymer Inorganic Chemistry Metal chemistry.chemical_compound Crystallography Deprotonation chemistry visual_art Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Triazene Metallocene Tetrahydrofuran Monoclinic crystal system |
| Zdroj: | Inorganica Chimica Acta. 359:2309-2313 |
| ISSN: | 0020-1693 |
| Popis: | Deprotonated 3-(2-fluorophenyl)-1-(4-acetylphenyl)triazene reacts with Hg(CH 3 COO) 2 in tetrahydrofuran to give light yellow crystals of [Hg II (RPhNNNPhR′) 2 ] n (R = acetyl, R′ = F). The new polymeric triazenide complex of Hg(II) belongs to the monoclinic space group C 2/ c . The lattice of [Hg II (RPhNNNPhR′) 2 ] n can be viewed as a bidimensional assembly of planar tectons [Hg II (RPhNNNPhR′) 2 ], occurring through metallocene alike Hg(II)-η 2 ,η 2 -arene π-interactions along the crystallographic axis b and non classical C–H⋯O bonding along the axis a . |
| Databáze: | OpenAIRE |
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