Synthesis and Structural Characterisation of 2-Acetylthiophene Salicylaldazine Complexes of Some Bivalent Transition Metal Ions

Autor:	Brajesh K. Singh, U. R. Singh
Rok vydání:	1992
Předmět:	Chemistry 2-acetylthiophene Bivalent (genetics) Transition metal ions Inorganic Chemistry Metal Azine Crystallography Tetragonal crystal system chemistry.chemical_compound visual_art visual_art.visual_art_medium Orthorhombic crystal system Physical and Theoretical Chemistry Spectral data
Zdroj:	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 22:247-258
ISSN:	1532-2440 0094-5714
DOI:	10.1080/00945719208021386
Popis:	Metal(Il) complexes, M(ats)2 [M = Mn, Co, Ni, Cu and Zn; Hats = 2-acetylthiophenesalicylaldazine] have been prepared and characterized, Magnetic and spectral data such as electronic, ESR and IR are used to establish the stereochemistry and mode of bonding of azine in the complexes. A X-ray diffraction study suggests a tetragonal unit lattice for Co(ats)2 and orthorhombic unit lattice for Cu(ats)2 and Zn(ats)2.
Databáze:	OpenAIRE
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