Iron-Catalyzed Amination of Sulfides and Sulfoxides with Azides in Photochemical Continuous Flow Synthesis

Autor:	Marie Borduy, Hélène Lebel, Henri Piras
Rok vydání:	2016
Předmět:	010405 organic chemistry Chemistry Continuous flow Nitrene Iron catalyzed General Chemistry 010402 general chemistry Photochemistry 01 natural sciences Trichloroethoxysulfonyl azide Catalysis 0104 chemical sciences Stereospecificity Organic chemistry Amination
Zdroj:	ACS Catalysis. 6:1109-1112
ISSN:	2155-5435
DOI:	10.1021/acscatal.5b02495
Popis:	A photochemical (UVA) continuous flow process for the amination of thioethers and sulfoxides was performed with trichloroethoxysulfonyl azide in the presence of catalytic iron(III) acetylacetonate. Aromatic and aliphatic sulfilimines and sulfoximines were produced in high yields and short reaction times. The reaction with chiral sulfoxides was stereospecific, producing enantioenriched sulfoximines in excellent yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::de6c9e8a11fe31b6f21278a299d7aa4c https://doi.org/10.1021/acscatal.5b02495 Zobrazit plný text záznamu