Mechanistic details for oxidative addition of PhICl2 to gold(i) complexes

Autor:	Farshad Shiri, Alireza Ariafard
Rok vydání:	2023
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 59:4668-4671
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d3cc00543g
Popis:	Our study discovered a new stepwise mechanism for the oxidative addition of PhICl2 to LAuAr. Fewer electron-withdrawing substituents on the Ar ligand increase the energy of Au(i) dx2−y2 orbital, making the reaction easier to achieve.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::de51641367cfceb22a03f79d3dc83dee https://doi.org/10.1039/d3cc00543g Zobrazit plný text záznamu