2-Chlorophenol degradation by catalytic wet air oxidation using copper supported on TiO2-CeO2-ZrO2
| Autor: | Luis Enrique García-Hernández, Adrián Cervantes-Uribe, Dora Ma. Frías-Márquez, Hermicenda Pérez-Vidal, J. G. Torres-Torres, Adib A. Silahua-Pavón, J. Carlos Arévalo-Pérez, Ma. Antonia Lunagómez-Rocha, J. Gpe Pacheco-Sosa |
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| Rok vydání: | 2019 |
| Předmět: |
Reaction mechanism
Environmental Engineering Materials science Diffuse reflectance infrared fourier transform Scanning electron microscope chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Copper 0104 chemical sciences Catalysis chemistry.chemical_compound Physisorption chemistry 2-Chlorophenol Wet oxidation 0210 nano-technology Water Science and Technology Nuclear chemistry |
| Zdroj: | Water Science and Technology. 80:911-919 |
| ISSN: | 1996-9732 0273-1223 |
| DOI: | 10.2166/wst.2019.330 |
| Popis: | In this work, we describe the morphological, electronic and catalytic properties of support TiO2-CeO2-ZrO2, prepared by sol–gel method, which was impregnated with copper at 5 and 10% by weight, in order to obtain efficient catalysts in the catalytic wet air oxidation (CWAO) of 2-cp. The catalysts were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM-EDS), UV-Vis diffuse reflectance spectroscopy (DRS) and nitrogen physisorption by the Brunauer-Emmett-Teller (BET) method. The activity of the materials used in this study revealed that without the presence of Cu, the SCO2 is low and with a content of 10% this metal shows the best catalytic behaviour; conversely, a reaction mechanism is proposed that describes the complete oxidation of 2-cp in this case. |
| Databáze: | OpenAIRE |
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