Autor:	David E. Cane, Manish Tandon
Rok vydání:	1994
Předmět:	biology Streptomycetaceae Stereochemistry Organic Chemistry Epicubenol biology.organism_classification Sesquiterpene Biochemistry Streptomyces chemistry.chemical_compound Biosynthesis chemistry Drug Discovery Actinomycetales Epicubenol synthase Incubation
Zdroj:	Tetrahedron Letters. 35:5355-5358
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)73498-8
Popis:	Incubation of [6-2H]FPP (14a) with epicubenol synthase isolated from Streptomyces sp. LL-B7 gave epicubenol (1c) labeled at D-9 as established by 2H NMR. These results confirm the involvement of a predicted 1,2-hydride shift in the mechanism of formation of 1.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::de39238889bb74a57db33f9744fb2788 https://doi.org/10.1016/s0040-4039(00)73498-8 Zobrazit plný text záznamu