Preparation of [Et2InSb(SiMe3)2]3; a trimeric single-source precursor to indium antimonide

Autor:	Richard L. Wells, Richard J. Jouet, Edward E. Foos, Peter S. White
Rok vydání:	2000
Předmět:	Dimer Indium antimonide Organic Chemistry Thermal decomposition Solid-state Trimer Crystal structure Ring (chemistry) Biochemistry Nanocrystalline material Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Materials Chemistry Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 598:182-186
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(99)00674-9
Popis:	The 1:1 mole ratio reaction of Et 2 InCl with Sb(SiMe 3 ) 3 results in the formation of [Et 2 InSb(SiMe 3 ) 2 ] 3 ( 1 ), a trimeric compound containing a six-membered indium–antimony ring. An X-ray crystal structure has been obtained for the compound substantiating the trimeric nature of 1 in the solid state, however variable-temperature 1 H-NMR studies show a dimer/trimer equilibrium for this species in solution. Preliminary thermolysis studies demonstrate its utility in the formation of nanocrystalline InSb.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::de30889ed7640c93e729769d07c8dcab https://doi.org/10.1016/s0022-328x(99)00674-9 Zobrazit plný text záznamu Full Text from ScienceDirect