RUNAWAY POTENTIAL AND PRESSURE RISE IN THE POLYMERIZATION OF STYRENE-BUTADIENE

Autor:	C. Siegmüller, F. Recasens, E. Velo
Rok vydání:	1992
Předmět:	Styrene-butadiene General Chemical Engineering Mass balance Thermodynamics Emulsion polymerization General Chemistry Kinetic energy Isothermal process law.invention chemistry.chemical_compound Polymerization chemistry law Heat transfer Distillation
Zdroj:	Chemical Engineering Communications. 117:455-476
ISSN:	1563-5201 0098-6445
Popis:	The safe operation of the batch emulsion polymerization of Styrene-Butadiene, with all reactants charged at the start, is studied. In order to assess runaway potential, simplified kinetic and headspace pressure models are developed. Kinetic information is obtained from isothermal reaction runs carried out over wide ranges of temperature (70 to 125°C) and pressures (8 to 23 bars). Detailed experimental setups and methods for both Butadiene distillation and reactor operation, are given for an industrial polymerization recipe. Simulation studies based on numerical integration of the heat and mass balance equations for cooled reactors show that for the relatively large particle size latex of this study, the reactor is not parametrically sensitive. The influence on the scaleup of the various heat transfer parameters, is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::de1dda8ca324d65d7b3c8c7afbf55ea6 https://doi.org/10.1080/00986449208936081 Zobrazit plný text záznamu