Sustainable nickel catalyst for the conversion of lignocellulosic biomass to H2-rich gas
| Autor: | Wojciech Franus, Rafał Panek, Joanna Goscianska, Kamila Przybysz, Jacek Grams, Robert Ryczkowski |
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| Rok vydání: | 2021 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Energy Engineering and Power Technology Lignocellulosic biomass chemistry.chemical_element 02 engineering and technology Coke Raw material 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Catalysis Nickel Fuel Technology Chemical engineering chemistry Fly ash Lanthanum 0210 nano-technology Zeolite |
| Zdroj: | International Journal of Hydrogen Energy. 46:10708-10722 |
| ISSN: | 0360-3199 |
| DOI: | 10.1016/j.ijhydene.2020.12.169 |
| Popis: | The objective of this paper was to design sustainable nickel catalysts supported on selected fly ash based zeolites to thermal processing of lignocellulosic feedstock towards hydrogen-rich gas. Moreover, in order to increase its catalytic performance in the studied process the catalyst supported on the most promising fly ash based zeolite was modified by selected rare-earth and transition metals (La, Pr, Ce, Y, Gd, Zr). The performed measurements exhibited that incorporation of nickel into the structure of zeolite A modified by lanthanum resulted in the most effective production of H2. The characterization of its physicochemical properties (XRD, TPR, SEM-EDS, TPD-NH3, BET and TGA-DTA) suggested that large pore size, moderate acidity, increased reducibility of an active phase and higher resistance to coke formation are the main factors responsible for increased activity of this catalyst. |
| Databáze: | OpenAIRE |
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