Transition-Metal-Catalyzed Alkenyl sp2 C–H Activation: A Short Account

Autor:	Teck-Peng Loh, Manikantha Maraswami
Rok vydání:	2019
Předmět:	chemistry.chemical_classification 010405 organic chemistry Alkene Organic Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences Transition metal chemistry Alkynylation Surface modification Chelation Selectivity
Zdroj:	Synthesis. 51:1049-1062
ISSN:	1437-210X 0039-7881
Popis:	Alkenes are ubiquitous in Nature and their functionalization continues to attract attention from the scientific community. On the other hand, activation of alkenyl sp2 C–H bonds is challenging due to their chemical properties. In this short account, we elucidate, discuss and describe the utilization of transition-metal catalysts in alkene activation and provide useful strategies to synthesize organic building blocks in an efficient and sustainable manner.1 Introduction2 Breakthrough3 Controlling E/Z, Z/E Selectivity3.1 Esters and Amides as Directing Groups3.2 The Chelation versus Non-Chelation Concept4 Other Alkene Derivatives5 Intramolecular C–H Activation6 Conclusion and Future Projects
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ddf6f5a82f7b92110ff185dc621c42d3 https://doi.org/10.1055/s-0037-1611649 Zobrazit plný text záznamu