Simple is best: Diamine zinc complexes as unexpected catalysts in lactide polymerisation

Autor:	Janna Börner, Ines dos Santos Vieira, Carsten Strohmann, Viktoria H. Gessner, Sonja Herres-Pawlis, Prisca K. Eckert
Rok vydání:	2013
Předmět:	chemistry.chemical_classification Lactide chemistry.chemical_element Zinc Chloride Catalysis Coordination complex Inorganic Chemistry chemistry.chemical_compound Monomer chemistry Bromide Diamine Polymer chemistry Materials Chemistry medicine Physical and Theoretical Chemistry medicine.drug
Zdroj:	Polyhedron. 49:151-157
ISSN:	0277-5387
Popis:	A series of monomeric coordination compounds containing zinc(II) chloride or zinc(II) bromide and the 1,2-diamine ligands TMEDA, TEEDA, (R,R)-TMCDA, (R,R)-TECDA and cis-TMCDA have been synthesised and structurally characterised using X-ray diffraction analysis. All but one complex could be successfully used as initiators for the solvent-free ring-opening polymerisation of d,l -lactide. In particular, the polylactide (PLA) prepared with compounds containing (R,R)-TECDA is obtainable in high yields with molecular weights suitable for industrial applications. Thus a class of stable, easy to synthesise and efficient PLA catalysts with neutral ligands is introduced.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ddda035d99b3f4f4217e4e31efdb1416 https://doi.org/10.1016/j.poly.2012.09.012 Zobrazit plný text záznamu Full Text from ScienceDirect