Epoxide and cyclic carbonate with diisononyl succinate backbone as phthalate-free plasticizers

Autor:	Benjamin Schäffner, Andreas Martin, Daniela Kruse, Angela Köckritz, Mykola Polyakov
Rok vydání:	2016
Předmět:	Triphosgene 010405 organic chemistry Organic Chemistry Phthalate Plasticizer Epoxide Tartrate 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences chemistry.chemical_compound chemistry Drug Discovery Carbonate Organic chemistry Carbonylation Derivative (chemistry)
Zdroj:	Tetrahedron Letters. 57:964-968
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2016.01.069
Popis:	Candidates for new phthalate-free plasticizers are synthesized based on epoxidized diisononyl maleate and carbonylated diisononyl tartrate. Although the carbonation of epoxidized diisononyl maleate with CO2 failed, the cyclic carbonate was synthesized successfully using triphosgene as carbonylation agent of the respective tartrate. The performance of the synthesized materials as plasticizer was analyzed under standard conditions as plastisols. Results showed potential for the epoxidized maleate and carbonylated derivative to be developed into phthalate free-plasticizers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ddcbe92aa0c7677cd4883e09e80e3c54 https://doi.org/10.1016/j.tetlet.2016.01.069 Zobrazit plný text záznamu Full Text from ScienceDirect