Conductive casting films based on an octasilicate-core dendrimer containing the mixed-valence state TCNQ on the periphery
| Autor: | Yasuyuki Irie, Megumi Komada, Hiroaki Imoto, Lina Li, Kensuke Naka, Takashi Nishino |
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| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Materials science Valence (chemistry) Ion exchange General Chemical Engineering Stacking 02 engineering and technology General Chemistry Conductivity 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Dendrimer Polymer chemistry Moiety 0210 nano-technology Acetonitrile Alkyl |
| Zdroj: | RSC Advances. 6:114513-114518 |
| ISSN: | 2046-2069 |
| Popis: | An octasilicate (OS)-core dendrimer terminated with imidazolium–7,7,8,8-tetracyanoquiodimethane (TCNQ) anion radicals (OS-mimTCNQ) was synthesized from an OS-core dendrimer having alkyl bromides as terminal groups (OS-mimBr) via anion exchange reaction with lithium TCNQ salt (LiTCNQ) in water. Conductive films were prepared by casting mixtures of OS-mimTCNQ with the neutral TCNQ in acetonitrile on glass substrates. Although the casting film of OS-mimTCNQ showed low conductivity ( |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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