Etch Rate Modification of SiO[sub 2] by Ion Damage

Autor: Rémy Charavel, Jean-Pierre Raskin
Rok vydání: 2006
Předmět:
Zdroj: Electrochemical and Solid-State Letters. 9:G245
ISSN: 1099-0062
DOI: 10.1149/1.2200307
Popis: Increased etch rate for implanted oxide with boron, phosphorus, arsenic, and argon is characterized for aqueous and vapor hydrofluoric acid (HF). Destruction by implantation of Si-O bonds makes oxide more reactive to HF. Water being reaction product and catalyst for oxide etching, its amount controls the reaction kinetic. In aqueous solution selectivity of four between implanted and unimplanted oxide is reached but increases up to 200 in vapor HF. In the case of HF etching under vapor phase the generated water increases the etch rate. This technique opens many process possibilities such as etch stop layer development, etching of buried trenches, definition of MEMS anchors, etc. (c) 2006 The Electrochemical Society.
Databáze: OpenAIRE