The system titanium-sulfur. I: The structure of Ti5S8 and the unit cells of Ti3S4 and Ti4S5

Autor:	G. A. Wiegers, F. Jellinek, E. Flink
Rok vydání:	2010
Předmět:	Chemistry Hexagonal crystal system Close-packing of equal spheres chemistry.chemical_element General Chemistry Trigonal crystal system Sulfur Metal Crystallography Octahedron visual_art Phase (matter) visual_art.visual_art_medium Titanium
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 85:869-872
ISSN:	0165-0513
DOI:	10.1002/recl.19660850903
Popis:	The structure of the phase Ti5S8 (rhombohedral) has been determined. It is based on a close packing of sulfur of the type cchh; the octahedral holes between adjacent cc sulfur layers and between adjacent hh layers are fully occupied by Ti, while the octahedral holes between adjacent ch layers are partly (1/5) occupied by metal atoms. The unit-cell dimensions of Ti3S4 (rhombohedral) and Ti4S5 (hexagonal or trigonal) are given.
Databáze:	OpenAIRE
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