Mass spectrometric study of the stereoisomers of 2-furyl- and 2-phenyldecahydro-4-quinolinone and their tertiary alcohols

Autor:	M. Z. Esenalieva, O. T. Zhilkibaev, K. D. Praliev, O. V. Agashkin, A. E. Lyuts, V. V. Zamkova
Rok vydání:	1986
Předmět:	chemistry.chemical_compound Molecular geometry chemistry Fragmentation (mass spectrometry) Organic Chemistry Mass spectrum Substituent Organic chemistry Alcohol Mass spectrometry Medicinal chemistry Dissociation (chemistry) Electron ionization
Zdroj:	Chemistry of Heterocyclic Compounds. 22:195-199
ISSN:	1573-8353 0009-3122
Popis:	A study was carried out on the major pathways for the decomposition of stereoisomers of 2-furyl- and 2-phenyldecahydro-4-quinolinone and their tertiary alcohol derivatives upon electron impact. The elemental composition of the characteristic ions was determined by high-resolution mass spectrometry. The introduction of a heavy substituent at C(2) leads to marked changes in the directions of the major fragmentation pathways of decahydroquinoline. The dependence of the probability for the formation of characteristic ions on the molecular geometry in the stereoisomer series was demonstrated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dd9535a082610a17c1646aafa5c60f9c https://doi.org/10.1007/bf00519943 Zobrazit plný text záznamu Full text from SpringerLink