EFFECT OF SURFACTANTS ON THE REDUCTION OF LEAD(II) IONS ON LEAD ELECTRODE

Autor:	A.B. Bayeshov, А.К. Mamyrbekova, M.К. Kassymova, A.D. Mamitova, O.N. Chechina
Rok vydání:	2020
Předmět:	Reduction (complexity) Chemistry 010401 analytical chemistry Inorganic chemistry Lead electrode 02 engineering and technology 021001 nanoscience & nanotechnology 0210 nano-technology 01 natural sciences 0104 chemical sciences Ion
Zdroj:	SERIES CHEMISTRY AND TECHNOLOGY. 2:129-137
ISSN:	2518-1491 2224-5286
Popis:	The effect high molecular weight water-soluble surfactants with different functional groups have on the electroreduction of lead(II) ions on a lead electrode in various electrolytes is studied. A copolymer of methacryloylaminophenol with acrylic acid, a leather waste hydrolyzate, and a copolymer of monoethanolamine with vinyl ether acetate are used as surfactants. The electrolytes that are used are 1 M KCl, KBr, KNO3, HCOONa, NH2SO3H, 0.5 M Na2SO4, and 0.35 M Na3C6H5O7 .2H2O. It is shown that in 1.0 M KCl or KBr solutions, there is no inhibition of the electroreduction of lead(II) ions by the adsorption layers of surfactants. It is found that the inhibitory effect of polymers on the electroreduction of lead(II) ions in different background electrolytes increases in the order KCl > KBr > Na3C6H5O7.2H2O > Na2SO4 > KNO3 > HCOONa > NH2SO3H. Key words: lead ions, electroreduction, surfactants, electrolyte, lead electrode, exchange current.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dd8fbe0f3b0f6e8c0798796f3ba61bfa https://doi.org/10.32014/2020.2518-1491.33 Zobrazit plný text záznamu