Solubility of ammonia in chloroform: analysis in terms of Henry's law and the equilibrium constant for hydrogen-bonded complex formation

Autor:	Loren G. Hepler, Charles Li, John F. Smith, Myron Roth
Rok vydání:	1989
Předmět:	Chloroform Hydrogen Organic Chemistry Complex formation chemistry.chemical_element Thermodynamics General Chemistry Solubility equilibrium Catalysis Henry's law Ammonia chemistry.chemical_compound chemistry Physical chemistry Solubility Equilibrium constant
Zdroj:	Canadian Journal of Chemistry. 67:2213-2217
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v89-344
Popis:	We have measured the solubility of ammonia in chloroform at several pressures and at three temperatures (25, 30, and 35 °C). Results of these measurements have been analysed in terms of the Henry's law constant that applies to "simple" dissolution of the type B(g) = B(dissolved) and the equilibrium constant K for the liquid phase complex-forming equilibrium represented by A + B = AB where A and B represent chloroform and ammonia, respectively. As expected on the basis of this analysis, ammonia is more soluble (same pressure and temperature) in chloroform than in carbon tetrachloride, where no hydrogen-bonded complex can be formed. Keywords: gas solubility, hydrogen-bonded complexes, Henry's law constant, ammonia–chloroform complex, chloroform-ammonia complex.
Databáze:	OpenAIRE
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