Liquid Crystal Solvents as Reaction Media for the Claisen Rearrangement

Autor:	W. E. Bacon, Glenn H. Brown
Rok vydání:	1969
Předmět:	Claisen rearrangement Chemistry Liquid crystal organic chemicals Intramolecular force Polymer chemistry Phenyl Ethers General Medicine General Chemistry Sigmatropic reaction Photochemistry Carroll rearrangement
Zdroj:	Molecular Crystals. 6:155-159
ISSN:	0369-1152
DOI:	10.1080/15421406908082956
Popis:	In the couse of our investigations of liquid crystals as solvents, we wish to report some kinetic data for the Claisen rearrangement. The thermal rearrangement of allyl phenyl ethers (1) proceeds by an intramolecular path to give an ortho-dienone (II) which rapidly enolizes to 2-allylphenols (III).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dd6533c112bb84d96a0c61e1cdbc022f https://doi.org/10.1080/15421406908082956 Zobrazit plný text záznamu