Blends of poly(ethylene oxide) and poly(4-vinylphenol-co-2-hydroxyethyl methacrylate): thermal analysis, morphological behaviour and specific interactions

Autor:	Robson Pacheco Pereira, C. E. Bielschowsky, Ana Maria Rocco
Rok vydání:	2003
Předmět:	Materials science Polymers and Plastics Ethylene oxide Organic Chemistry Oxide Methacrylate Miscibility chemistry.chemical_compound Crystallinity chemistry Polymer chemistry Poly-4-vinylphenol Materials Chemistry Polymer blend Glass transition
Zdroj:	Polymer. 44:361-368
ISSN:	0032-3861
DOI:	10.1016/s0032-3861(02)00786-3
Popis:	DSC and optical microscopy were used to determine the miscibility and crystallinity of blends of poly(ethylene oxide) (PEO) with poly(4-vinylphenol-co-2-hydroxyethyl methacrylate) (PVPh-HEM). A single glass transition temperature was observed for all blends, indicating miscibility. A progressive decrease in the degree of crystallinity and in the size of the PEO spherullites is observed, as PVPh-HEM is added. FTIR was used to probe the intermolecular specific interactions of the blends and the miscibility of the blend is mainly attributed to PVPh-HEM/PEO intermolecular interactions via hydrogen bonding.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dd4a5403c6d528a4aea75a2bd83c75eb https://doi.org/10.1016/s0032-3861(02)00786-3 Zobrazit plný text záznamu Full Text from ScienceDirect