Scheelite: a versatile structural template for selective alkene oxidation catalysts

Autor:	James F. Brazdil
Rok vydání:	2015
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Alkene Scheelite Organic chemistry Dehydrogenation Molybdate Acrylonitrile Ammoxidation Butene Catalysis
Zdroj:	Catalysis Science & Technology. 5:3452-3458
ISSN:	2044-4761 2044-4753
DOI:	10.1039/c5cy00387c
Popis:	The scheelite (CaWO4) structure type serves as the framework for a wide variety of metal oxide catalysts used for the selective oxidation and ammoxidation of alkenes. Among the industrially important processes where these catalysts find application are propylene oxidation to acrolein, propylene ammoxidation to acrylonitrile and butene oxidative dehydrogenation to butadiene. This review examines the body of work used to understand the structure-function relationship of bismuth molybdate scheelite catalysts in selective ammoxidation of propylene to acrylonitrile including the work on the unique bismuth–cerium molybdate solid solution series of selective ammoxidation catalysts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dd3e7f2535accce0eadce5e2c48a5d4d https://doi.org/10.1039/c5cy00387c Zobrazit plný text záznamu