ChemInform Abstract: Theoretical Study of the Relative Stabilities of the α/β3-[XW11O39]m-Lacunary Polyoxometalates (X: P, Si)

Autor:	Anna Proust, Hélène Gérard, Danielle Laurencin
Rok vydání:	2008
Předmět:	Metal Crystallography Chemistry visual_art visual_art.visual_art_medium Beta (velocity) General Medicine Structural difference Lacunary function Relative stability Ion
Zdroj:	ChemInform. 39
ISSN:	1522-2667 0931-7597
Popis:	A computational study of the relative stability of the monolacunary Keggin polyoxotungstates alpha and beta 3-[XW 11O 39] ( m- ) (X = P, m = 7; X = Si, m = 8) was performed. The influence of the nature of different grafted cations and of the central anion XO 4 ( n- ) on the relative stabilities of the lacunary isomers was analyzed. From these results, an interpretation of the structural difference in the metallic frameworks of alpha-[PW 11O 39{Ru(DMSO) 3(H 2O)}] (5-), alpha-[PW 11O 39{Ru(C 6H 6)(H 2O)}] (5-), and beta 3-[SiW 11O 39{Ru(DMSO) 3(H 2O)}] (6-) is proposed, and conclusions are drawn as to how to favor the formation of beta 3 derivatives in future syntheses.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dd263f06a4d2780d4f919085dfb27da6 https://doi.org/10.1002/chin.200846001 Zobrazit plný text záznamu Plný text