The Mass Spectra of 4-(3-Arylsydnonyl)Methanols and Their Derivatives: Formation of Ar-N=C-H Cation via a Hydrogen Migration

Autor:	Shaw‐Taolin, Ling-Ling Tien
Rok vydání:	1990
Předmět:	Hydrogen chemistry Stereochemistry Mass spectrum chemistry.chemical_element Cleavage (crystal) General Chemistry Medicinal chemistry
Zdroj:	Journal of the Chinese Chemical Society. 37:565-570
ISSN:	0009-4536
DOI:	10.1002/jccs.199000077
Popis:	Fourteen mass spectra of the sydnonylmethanols and their derivatives have been measured under EI conditions. The process of losing a OR' radical and hydrogen migration reaction are accompanyed with lost of a CO and an NO channel. The competition between cleavage of C-0 bond and hydrogen migration is mainly controlled by the type and size of the R' group.
Databáze:	OpenAIRE
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