Recent developments in ruthenium–nitrosoarene chemistry: Unconventional synthetic strategies, new ligand designs, and exploration of ligands redox non-innocence

Autor:	Chun-Yuen Wong, Siu-Chung Chan
Rok vydání:	2020
Předmět:	010405 organic chemistry Chemistry Ligand Nitrosonium chemistry.chemical_element 010402 general chemistry 01 natural sciences Redox Combinatorial chemistry 0104 chemical sciences Ruthenium Inorganic Chemistry chemistry.chemical_compound Materials Chemistry Physical and Theoretical Chemistry
Zdroj:	Coordination Chemistry Reviews. 402:213082
ISSN:	0010-8545
Popis:	This review describes the recent advances in ruthenium–nitrosoarene chemistry. The preparations of Ru–nitrosoarene complexes by (1) intermolecular nitrosonium insertion into Ru–aryl bonds, and (2) Ru-induced symmetric or asymmetric cleavage of benzofuroxan, are discussed. The exploration of the redox non-innocence of the coordinated nitrosoarene, dinitrosoarene and structurally related ligands via structural, spectroscopic, electrochemical and computational studies are presented.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dd1c1052f951a19542a44d93f5476805 https://doi.org/10.1016/j.ccr.2019.213082 Zobrazit plný text záznamu Full Text from ScienceDirect