Quaternary isobaric (vapor+liquid+liquid) equilibrium and (vapor+liquid) equilibrium for the system (water+ethanol+cyclohexane+heptane) at 101.3kPa

Autor: Vicente Gomis, Ana Pequenín, Juan Carlos Asensi
Rok vydání: 2011
Předmět:
Zdroj: The Journal of Chemical Thermodynamics. 43:1097-1103
ISSN: 0021-9614
DOI: 10.1016/j.jct.2011.02.016
Popis: Experimental isobaric (vapor + liquid + liquid) and (vapor + liquid) equilibrium data for the ternary system {water (1) + cyclohexane (2) + heptane (3)} and the quaternary system {water (1) + ethanol (2) + cyclohexane (3) + heptane (4)} were measured at 101.3 kPa. An all-glass, dynamic recirculating still equipped with an ultrasonic homogenizer was used to determine the VLLE. The results obtained show that the system does not present quaternary azeotropes. The point-by-point method by Wisniak for testing the thermodynamic consistency of isobaric measurements was used to test the equilibrium data.
Databáze: OpenAIRE