Quaternary isobaric (vapor+liquid+liquid) equilibrium and (vapor+liquid) equilibrium for the system (water+ethanol+cyclohexane+heptane) at 101.3kPa
Autor: | Vicente Gomis, Ana Pequenín, Juan Carlos Asensi |
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Rok vydání: | 2011 |
Předmět: | |
Zdroj: | The Journal of Chemical Thermodynamics. 43:1097-1103 |
ISSN: | 0021-9614 |
DOI: | 10.1016/j.jct.2011.02.016 |
Popis: | Experimental isobaric (vapor + liquid + liquid) and (vapor + liquid) equilibrium data for the ternary system {water (1) + cyclohexane (2) + heptane (3)} and the quaternary system {water (1) + ethanol (2) + cyclohexane (3) + heptane (4)} were measured at 101.3 kPa. An all-glass, dynamic recirculating still equipped with an ultrasonic homogenizer was used to determine the VLLE. The results obtained show that the system does not present quaternary azeotropes. The point-by-point method by Wisniak for testing the thermodynamic consistency of isobaric measurements was used to test the equilibrium data. |
Databáze: | OpenAIRE |
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