Spectroelectrochemistry in Melts: Applications to Molten Chloroaluminates

Autor: V. E. Norvell, Gleb Mamantov, Leon N. Klatt
Rok vydání: 1980
Předmět:
Zdroj: Journal of The Electrochemical Society. 127:1768-1772
ISSN: 1945-7111
0013-4651
DOI: 10.1149/1.2129998
Popis: Spectroelectrochemistry is an effective approach to studies of redox chemistry in solutions. uv-visible spectroelectrochemical studies in molten chloroaluminates (AlCl/sub 3/--NaCl mixtures) were initiated using a silicon vidicon rapid-scan spectrometer. Electrodes made from glassy carbon foam and metal grids are used in optically transparent thin layer cells. The solute species of interest are the oxidation products of sulfur and some of the Group IVB--VIB transition metal ions. The apparatus and the initial results are described.
Databáze: OpenAIRE