Spectroelectrochemistry in Melts: Applications to Molten Chloroaluminates
Autor: | V. E. Norvell, Gleb Mamantov, Leon N. Klatt |
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Rok vydání: | 1980 |
Předmět: |
Silicon
Renewable Energy Sustainability and the Environment Inorganic chemistry chemistry.chemical_element Halide Glassy carbon Condensed Matter Physics Electrochemistry Redox Chemical reaction Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal chemistry visual_art Electrode Materials Chemistry visual_art.visual_art_medium |
Zdroj: | Journal of The Electrochemical Society. 127:1768-1772 |
ISSN: | 1945-7111 0013-4651 |
DOI: | 10.1149/1.2129998 |
Popis: | Spectroelectrochemistry is an effective approach to studies of redox chemistry in solutions. uv-visible spectroelectrochemical studies in molten chloroaluminates (AlCl/sub 3/--NaCl mixtures) were initiated using a silicon vidicon rapid-scan spectrometer. Electrodes made from glassy carbon foam and metal grids are used in optically transparent thin layer cells. The solute species of interest are the oxidation products of sulfur and some of the Group IVB--VIB transition metal ions. The apparatus and the initial results are described. |
Databáze: | OpenAIRE |
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