Nickel mediated sulfur–selenium and sulfur–sulfur bond formation
Autor: | Chia-Huei Lai, Marcetta Y. Darensbourg, Joseph H. Reibenspies |
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Rok vydání: | 1999 |
Předmět: |
inorganic chemicals
Chemistry Electrophilic addition Ligand Intermolecular force Metals and Alloys chemistry.chemical_element General Chemistry Bond formation Photochemistry Sulfur Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Nickel Polymer chemistry otorhinolaryngologic diseases Materials Chemistry Ceramics and Composites Selenium |
Zdroj: | Chemical Communications. :2473-2474 |
ISSN: | 1364-548X 1359-7345 |
DOI: | 10.1039/a903973b |
Popis: | Electrophilic addition of the PhSeCl to a nickel dithiolate yields S,S′-bis(phenylselenenyl-N,N′-bis(mercaptoethyl)-1,5-diazacyclooctane nickel(II) dichloride and a dimeric, intermolecular bis-disulfide which results from ligand oxidation. |
Databáze: | OpenAIRE |
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