Bimolecular homolytic reactions of alkylcobalt complexes

Autor:	Shaoyung Lee, Tsung Yao Ku
Rok vydání:	2007
Předmět:	chemistry.chemical_classification Reaction mechanism Aqueous solution Ligand Kinetics chemistry.chemical_element Photochemistry Medicinal chemistry Homolysis Inorganic Chemistry chemistry Materials Chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Carbon Alkyl
Zdroj:	Polyhedron. 26:2901-2905
ISSN:	0277-5387
DOI:	10.1016/j.poly.2007.01.032
Popis:	The reactions of RCoL1(H2O)2+ (R = CH3, C2H5 and n-C3H7; L1 = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and CH3CoL2(H2O)2+ (L2 = 1,4,8,11-tetraazacyclotetradecane) with Cr2+ in aqueous solution were studied. The reaction products were CoL 1 ( H 2 O ) 2 2 + (or CoL 2 ( H 2 O ) 2 2 + ) and RCr2+, following which the related alkanes were obtained via acidolysis. The reaction mechanism appears to consist of an SH2 displacement at the saturated carbon. The reactivity is clearly dependent on the size of the alkyl group, the ligand and the configuration of the complex. The kinetics for this reaction were also studied at various temperatures. The reaction of RCoL1(H2O)2+ with V2+ was investigated as well in this study.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dc90d7ec576a3c1ffc2b6530e1c61e9e https://doi.org/10.1016/j.poly.2007.01.032 Zobrazit plný text záznamu Full Text from ScienceDirect