Microwave‐Enhanced Ferrier Reaction: A Facile Synthesis of 2,3‐Unsaturated‐O‐Glycosides Under Solvent‐Free Conditions

Autor:	Wenting Du, Yong‐Zhou Hu
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Ferrier carbocyclization chemistry.chemical_compound Ferrier rearrangement Solvent free Chemistry Silica gel Organic Chemistry Organic chemistry Glycoside Glucal Microwave Catalysis
Zdroj:	Synthetic Communications. 36:2035-2046
ISSN:	1532-2432 0039-7911
Popis:	A variety of 2,3‐unsaturated‐O‐glycosides have been prepared by the Ferrier rearrangement of acetyl protected glycals under microwave irradiation using silica gel as an acid catalyst. Environmental friendliness, high yields, and short reaction times are the key features of this method. Furthermore, the method was applicable not only to the Ferrier reaction of 3,4,6‐tri‐O‐acetyl glucal and 3,4,6‐tri‐O‐acetyl galactal but also to the Ferrier reaction of 3,4‐di‐O‐acetyl arabinal.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dc7d4b3cb00c81409383c2505c665de8 https://doi.org/10.1080/00397910600634415 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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