ChemInform Abstract: Ionic Liquid-Promoted Stereoselective Synthesis of (Z)-Vinyl Bromides by [bmIm]OH under Organic Solvent-Free Conditions: A Green Approach

Autor:	Jhinuk Gupta, Brindaban C. Ranu, Subhash Banerjee
Rok vydání:	2008
Předmět:	Green chemistry chemistry.chemical_classification chemistry.chemical_compound Base (chemistry) chemistry Organic solvent Polymer chemistry Ionic liquid Hydroxide Stereoselectivity General Medicine Organic solvent free
Zdroj:	ChemInform. 39
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200806056
Popis:	A simple and easily accessible ionic liquid, 1‐butyl‐3‐methylimidazolium hydroxide ([bmIm]OH), has been demonstrated as an efficient promoter and reaction medium for the highly stereoselective synthesis of (Z)‐vinyl bromides by the debrominative decraboxylation of dibrominated α,β‐unsaturated carboxylic acids in high yields. The reaction does not require either a conventional base or an organic solvent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dc467222b527218578426520ae2ddc90 https://doi.org/10.1002/chin.200806056 Zobrazit plný text záznamu Plný text