A new environmentally-friendly route to in situ form a high-corrosion-resistant nesquehonite film on pure magnesium
| Autor: | Hongda Deng, Youkun Yang, Quanyou Ren, Xianlong Cao, Xianglong Hou, Wei Lan, Daliang Yu, Fusheng Pan, Jie Hu, Yongbo Yan |
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| Rok vydání: | 2020 |
| Předmět: |
Materials science
Magnesium General Chemical Engineering Carbonation Substrate (chemistry) chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences 0104 chemical sciences Corrosion Metal Chemical engineering chemistry visual_art Phase (matter) visual_art.visual_art_medium 0210 nano-technology Porosity |
| Zdroj: | RSC Advances. 10:35480-35489 |
| ISSN: | 2046-2069 |
| Popis: | Magnesium-based materials are promising lightweight structural materials due to their excellent properties. However, their extensive application has been severely limited due to their high corrosion susceptibility. The inadequate corrosion resistance of Mg is mainly attributed to the porous and unprotective native surface film formed on Mg in aggressive environments. Here, we demonstrated a new environment-friendly route for the growth of a continuous nesquehonite (MgCO3·3H2O) protective film on the surface of pure Mg metal at a relatively low temperature via an in situ reaction of the Mg surface with gaseous phase CO2 in humid environments. The protective film consists solely of highly crystalline MgCO3·3H2O that is compact and has an umbrella-like structure. Electrochemical tests showed that compared to the untreated Mg substrate, the protective film can effectively improve the corrosion resistance of the substrate by nearly two orders of magnitude. Additionally, a possible formation mechanism of the nesquehonite film on the pure Mg was proposed and the effect of the carbonation time on the film was investigated. This environmentally-friendly surface treatment method is promising for use in the protection of magnesium-based materials. |
| Databáze: | OpenAIRE |
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